If you use Chrome as your personal web browser, in order to keep accounts separate (work/personal), it is recommended that you create a work profile to house all of your work shortcuts, accounts and settings.
Click on your profile icon in the upper right-hand side of Chrome - under profiles, select "+ Add"
A new window will appear. To continue quickly, select "Continue without an account"
From here follow the instructions on finishing setting up your new profile - make sure to name it "Work" or something that will be different from what your personal profile.
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To switch back and forth from one profile to the next - simply select the profile icon and select the profile you want to access.